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- W1505056799 abstract "Following our general approach to Λ-doubling specificity in the capture of dipolar molecules by ions [M. Auzinsh et al., J. Chem. Phys. 128, 184304 (2008)], we calculate the rate coefficients for the title process in the temperature range 10−4<T<102 K. Three regimes considered are as follows: (i) nonadiabatic capture in the regime of high-field Stark effect with respect to the Λ-doubling components, (10−1<T<102 K), (ii) adiabatic capture in the regime of intermediate Stark effect (10−3<T<10−1 K), and (iii) adiabatic capture in the limit of very low temperatures (T⪡10−3 K) in the regime of quadratic Stark effect with respect to the Λ-doubling and hyperfine components. The results predict a high specificity of the capture rates with respect to the Λ-doublet states even under conditions when the collision energy of the partners strongly exceeds the Λ-doubling splitting." @default.
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- W1505056799 date "2009-01-06" @default.
- W1505056799 modified "2023-10-16" @default.
- W1505056799 title "Lambda-doublet specificity in the low-temperature capture of NO(X Π21/2) in low rotational states by C+ ions" @default.
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- W1505056799 doi "https://doi.org/10.1063/1.3043365" @default.
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