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- W1505176185 endingPage "287" @default.
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- W1505176185 abstract "Observed sedimentation velocities in solutions of unknown microstructure can be misleading. Sedimentation-velocity behavior is governed by the interplay of three factors: buoyant density, molecular weight or particle mass, and solution nonideality. As a result, nonideal molecular solutions near a plait point can sediment with fronts as sharp as those of ideal solutions of massive colloidal particles. In addition, because phenomenological transport coefficients increase without bound near a consolute point, or plait point, sedimentation velocities can be as high in near-critical molecular solutions as in colloidal mixtures. Sedimentation profiles computed for model nonideal, molecular solutions are reported here; these profiles resemble those of colloids, and micelle sizes computed in the usual way from these profiles appear deceptively reasonable. Hence caution is needed when inferring from sedimentation profiles the nature of microstructures present in solution." @default.
- W1505176185 created "2016-06-24" @default.
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- W1505176185 date "1986-09-01" @default.
- W1505176185 modified "2023-10-16" @default.
- W1505176185 title "Sedimentation of molecular solutions in the ultracentrifuge" @default.
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- W1505176185 doi "https://doi.org/10.1016/0021-9797(86)90227-4" @default.
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