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- W1505215094 abstract "Bimetallic Zr complexes are synthesized by olefin metathesis reaction of vinyl group of monometallic complexes. The Si bridged zirconocene {η5-C5Me4-SiMe2-η5-C5H3CH2CH = CH2}ZrCl2 is transformed by metathesis reaction to the novel bimetallic complex with ansa-structure. Ethylene and propylene polymerization was conducted by bimetallic complexes. The activity of the bimetallic complex depends on the steric hindrance of the ligand. The bimetallic complex with ansa-structure gave isotactic polypropylene with a similar high selectivity to that of the monometallic analog. Bimetallic complexes catalyzed cyclopolymerization of 1,5-hexadiene to give poly(methylene-l ,3-cyclopentane)." @default.
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- W1505215094 date "2006-01-01" @default.
- W1505215094 modified "2023-10-15" @default.
- W1505215094 title "Olefin Polymerization by Bimetallic Zr Catalyst. Ligand Effect for Activity and Stereoselectivity" @default.
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- W1505215094 doi "https://doi.org/10.1016/s0167-2991(06)80444-1" @default.
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