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- W15052860 abstract "The authors have studied the reactions of alkyl trimethylsilyl phosphonites with alkoxyacetylenes. The use of excess of alkoxyacetylenes in the reactions leads to the formation of double addition products: the phosphinates. Such a course of reaction is determined by the presence in the phosphonites of two fragments, P-H and Si-O-P, each of which has fairly high reactivity toward activated multiple bonds. The IR spectra were determined on a UR-20 spectrometer (NaCl), and the /sup 1/H, /sup 13/C, and /sup 31/P NMR spectra on a JEOL FX-100 spectrometer with TMS and an 85% solution of H/sub 3/PO/sub 4/ in D/sub 2/O as standards." @default.
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- W15052860 date "1987-12-10" @default.
- W15052860 modified "2023-09-28" @default.
- W15052860 title "Reactions of alkyl trimethylsilyl phosphonites with alkoxyacetylenes" @default.
- W15052860 hasPublicationYear "1987" @default.
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