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- W1506020938 abstract "Abstract Exchange reactions between ( E )-2-dimethyl(chloro)stannyl-3-diethylboryl-2- butene ( 1 ) and various trimethyl(organyl)stannanes ( 2 , 3 ) have been studied. If the organyl group R is Ph, C 5 H 5 , 2-thienyl or 3-thienyl ( 2a–d ), then the exchange process is accompanied by numerous side reactions. In this case, reaction of 1 with the corresponding organyl lithium compounds is preferable. However, if the organyl group is an alkynyl group (CCt-Bu, CCSiMe 3 , CCSnMe 3 ) ( 3 ) the elimination of Me 3 SnCl leads to new stannacyclopentadienes carrying different substituents. The products are characterized by 1 H, 13 C, 11 B, 29 Si, and 119 Sn NMR spectroscopy." @default.
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- W1506020938 date "1988-01-01" @default.
- W1506020938 modified "2023-10-12" @default.
- W1506020938 title "Organoborierung von Alkinylstannanen" @default.
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- W1506020938 doi "https://doi.org/10.1016/0022-328x(88)80502-3" @default.
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