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- W1506543286 abstract "A purpose-built spectroelectrochemical cell for in situ fluorescence XAFS (X-ray Absorption Fine Structure) measurements of bulk solution species during constant-potential electrolysis is described. The cell performance was demonstrated by the collection of europium L{sub 3}-edge XANES (X-ray Absorption Near Edge Structure) throughout the course of electrolysis of an aqueous solution of EuCl{sub 3}{center_dot}6H{sub 2}O in 1 M H{sub 2}SO{sub 4}. The europium L{sub 3}-edge resonances reported here for the Eu{sup III} and Eu{sup II} ions demonstrate that their 2p{sub 3/2} {yields} 5d electronic transition probabilities are not the same." @default.
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- W1506543286 date "1995-06-12" @default.
- W1506543286 modified "2023-09-26" @default.
- W1506543286 title "Solution spectroelectrochemical cell for in situ X-ray absorption fine structure" @default.
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- W1506543286 doi "https://doi.org/10.2172/515522" @default.
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