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• W1506577612 abstract "Chloromethane, a gaseous natural product implicated in methylation processes in Phellinus pomaceus , has been shown to act as methyl donor in veratryl alcohol biosynthesis in the lignin-degrading fungi Phanerochaete chrysosporium, Phlebia radiata , and Coriolus versicolor , none of which released detectable amounts of CH 3 Cl during growth. When P. chrysosporium was grown in a medium containing C 2 H 3 Cl, levels of C 2 H 3 incorporation into the 3- and 4- O -methyl groups of veratryl alcohol were very high and initially similar to those observed when the medium was supplemented with l -[ methyl - 2 H 3 ]methionine. When C 2 H 3 Cl was added to cultures actively synthesizing veratryl alcohol, incorporation of C 2 H 3 was very rapid, with 81% of veratryl alcohol labeled after 12 h. By contrast, incorporation of C 2 H 3 from l -[ methyl - 2 H 3 ]methionine was comparatively slow, attaining 10% after 12 h. It is proposed that these lignin-degrading fungi possess a tightly channeled multienzyme system in which CH 3 Cl biosynthesis is closely coupled to CH 3 Cl utilization for methylation of veratryl alcohol precursors." @default.
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• W1506577612 date "1990-11-01" @default.
• W1506577612 modified "2023-09-25" @default.
• W1506577612 title "Chloromethane, Methyl Donor in Veratryl Alcohol Biosynthesis in <i>Phanerochaete chrysosporium</i> and Other Lignin-Degrading Fungi" @default.
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• W1506577612 doi "https://doi.org/10.1128/aem.56.11.3450-3457.1990" @default.
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