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- W1506579183 endingPage "470" @default.
- W1506579183 startingPage "429" @default.
- W1506579183 abstract "The strategy employing the cycloreversion reaction in the final step is a very powerful method for the preparation of highly conjugated compounds, which are so far unknown, difficult to access, intractable to purify, or impossible to measure. In this chapter, successful examples of such retro-Diels-Alder (rDA) approaches as well as the cheletropic cycloreversion are discussed by sorting the types of targeted large π-systems. Topics discussed include π-system expansion of porphyrinoids, π-expansion of porphyrazines and phthalocyanines, π-fusion of porphyrin oligomers, π-fusion of porphyrin and polycyclic aromatic hydrocarbons, π-expansion and fusion of boron-dipyrromethenes (BODIPYs), π-expansion of miscellaneous compounds based on bicyclo[2.2.2]octadiene (BCOD)-fused pyrroles, and π-system construction of acenes." @default.
- W1506579183 created "2016-06-24" @default.
- W1506579183 creator A5084039421 @default.
- W1506579183 date "2014-01-10" @default.
- W1506579183 modified "2023-10-14" @default.
- W1506579183 title "Cycloreversion Approach For Preparation of Large π‐Conjugated Compounds" @default.
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