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- W1506693359 abstract "The caprolactam polymerization process in the presence of the hydrazine derivatives has been investigated. During polymerization of ∈-caprolactam in the presence of these initiators an induction period was observed in all cases due to formation of the product of the interaction of caprolactam with the initiator. The induction period and the molecular weight were ascertained to decrease with increase in the initiator's content. The initiator penetrates into macromolecular chain and thus regulates its molecular weight. The reaction rate was shown to be proportional to the square root of the initiator concentration. The given process obeys the kinetic regularities of a reversible first order reaction with respect to the monomer concentration and it agrees with the Arrhenius equation. On the basis of this investigation the scheme of the process was suggested and the constants of the initiation and the chain growth rate were calculated." @default.
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- W1506693359 date "1967-01-01" @default.
- W1506693359 modified "2023-09-25" @default.
- W1506693359 title "Investigation of the∈-caprolactam polymerization process in the presence of hydrazine derivatives" @default.
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- W1506693359 doi "https://doi.org/10.1002/polc.5070160625" @default.
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