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- W1506771986 abstract "Reactions of poly(N-alkyliminoalanes) (PIA) such as (HAlN-t-Bu)4, (HAlN-i-Pr)4, (HAlN-i-Pr)6 and (HAlN-n-Pr)8 with HCl, HgCl2 and TiCl4 have been investigated. Two reaction paths are observed which involve either the simple substitution of hydridic hydrogens with chlorine or the same reaction accompanied by the cleavage of AlN bonds with subsequent rearrangement of the molecular structure of the PIA. In both cases the reaction depends on the chlorination agent and the molecular features of the poly(N-alkyliminoalanes). Poly(N-alkyliminoalanes) have been obtained with partial and complete chlorination that include (ClAlN-t-Bu)4, (ClAlN-iPr)4, (ClAlN-i-Pr)6, which were separated as crystalline products and fully characterized." @default.
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- W1506771986 date "1976-03-01" @default.
- W1506771986 modified "2023-10-18" @default.
- W1506771986 title "The chemistry and the stereochemistry of poly(N-alkyliminoalanes)" @default.
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- W1506771986 doi "https://doi.org/10.1016/s0022-328x(00)94444-9" @default.
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