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- W1506775605 abstract "Abstract Flash photolysis of W(CO) 6 results in W(CO) 5 (λ max 414 nm) and CO in a one step-reaction. These products are able to react in several ways depending on the solvent used: in cyclohexane a slow thermal reaction is observed resulting in the original W(CO) 6 ( k 2 89 l mol −1 sec −1 ); in CCl 4 a new compound W(CO) 5 Cl (λ max 385 nm) is formed rapidly ( k 1 232 sec −1 ) by a complex reaction involving interaction between CO and CCl 4 ; in the mixed solvent CCl 4 /C 6 H 12 the formation of W(CO) 5 Cl is the predominant step. These results have been interpreted with regard to the rate of metathesis of olefins." @default.
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- W1506775605 date "1976-03-01" @default.
- W1506775605 modified "2023-10-16" @default.
- W1506775605 title "Reaction de metathese des olefines induite photochimiquement en presence d'un complexe de metal de transition" @default.
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- W1506775605 doi "https://doi.org/10.1016/s0022-328x(00)82140-3" @default.
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