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- W1507122306 abstract "A common procedure for toughening of polymeric materials is to blend them with secondphase rubber particles. A toughening-criterion proposed by Wu [1] states that a sharp brittle/tough transition occurs for nylon/rubber blends when the average interparticle matrix ligament thickness is reduced below a critical value. A physical explanation of the absolute length parameter was offered by Muratoglu et al. [2], who recognized the brittle/tough transition as a true material feature, which was attributed to thin layers of preferentially oriented material, with a reduced plastic resistance. This local anisotropy is due to the crystallization behavior of the matrix which is influenced by the rubber/matrix interface, leading to a layer of parallel crystalline lamellae, with the crystalline planes having the lowest plastic resistance parallel to the interface. Bartczak et al. [3,4] generalized the Wu criterion to high density polyethylene (HDPE) and showed the critical interparticle distance to be an intrinsic property of the matrix material, thereby opening the possibility of using mineral fillers for the toughening of semicrystalline polymers, the advantage of which would be an improved modulus of the blend." @default.
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- W1507122306 date "2003-01-01" @default.
- W1507122306 modified "2023-09-27" @default.
- W1507122306 title "Multiscale modeling of particle-modified semicrystalline materials" @default.
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