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• W1507274015 startingPage "192" @default.
• W1507274015 abstract "This work, besides its fundamental interest is mainly motivated by the atmospheric importance of formaldehyde. The 10-μm region is indeed a possible spectral domain for the detection of this molecule in the atmosphere and no line parameters are presently available in the atmospheric databases for H2CO in this spectral range. Using the experimental data available in the literature for the ν3, ν4, and ν6 bands [J. Chem. Phys. 91 (1989) 646 and references therein] and for the ν2 band [J. Mol. Spectrosc. 96 (1982) 353 and references therein] and adequate theoretical models it proved possible to reproduce satisfactorily the experimental data and to generate a list of line positions and intensities for the 5–10 μm region. The Hamiltonian model accounts for the various Coriolis-type resonances which perturb the energy levels of the 31, 41, and 61 vibrational states as well as for the weaker anharmonic resonances coupling the 21 and 31 energy levels. This is also the case for the line intensity calculations which allow one to reproduce satisfactorily the line by line intensity measurements as well as the integrated intensities available in the literature." @default.
• W1507274015 created "2016-06-24" @default.
• W1507274015 creator A5026100116 @default.
• W1507274015 creator A5027901331 @default.
• W1507274015 creator A5051202924 @default.
• W1507274015 date "2003-10-01" @default.
• W1507274015 modified "2023-09-30" @default.
• W1507274015 title "New analysis of the ν2, ν3, ν4, and ν6 bands of formaldehyde H212C16O line positions and intensities in the 5–10μm spectral region" @default.
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• W1507274015 doi "https://doi.org/10.1016/s0022-2852(03)00207-8" @default.
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