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- W1507331989 abstract "A new procedure for the desymmetrization of prochiral 3-substituted cyclobutanones has been established through organocatalyzed Michael addition to nitroalkenes. The approach provides enantiomerically enriched 2-alkyl-3-aryl(alkyl) cyclobutanones with three contiguous stereogenic centers. The optimum conditions were determined by screening of catalyst and reaction conditions and a transition-state model is proposed to account for the observed diastereomeric and enantiomeric selectivities." @default.
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- W1507331989 date "2014-11-11" @default.
- W1507331989 modified "2023-09-25" @default.
- W1507331989 title "Enantioselective Organocatalyzed Desymmetrization of 3-Substituted Cyclobutanones through Michael Addition to Nitroalkenes" @default.
- W1507331989 doi "https://doi.org/10.1055/s-0034-1379489" @default.
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