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- W1507808049 abstract "Self-assembly employs pre-existing components “pre-programmed” to, spontaneously, organize under the influence of normally noncovalent bonding interactions, such as hydrogen bonding, π–π interactions, hydrophobic interactions, electrostatic forces, capillarity, etc. For example, amphiphilic molecules, composed of hydrophilic and hydrophobic parts, when added to water plus oil, organize into micelles and, at higher concentrations, spatially extensive periodic networks with hexagonal, cubic, bicontinuous, or lamellar arrangements. Calcination or extraction of the amphiphilic surfactant assemblies then yields so-called mesoporous materials characterized by periodic networks of monosized pores with 2- or 3-D connectivities. Although the original MCM (mobil composition of matter) materials were mesoporous silica powders, a significant effort has been made during the past 12 years to prepare mesoporous films, spherical and other well-defined shapes, and hierarchical assemblies. It is also now recognized that amphilphile self-assembly conducted in the presence of both hydrophilic inorganic and hydrophobic organic precursors provides a viable route to the formation of hybrid inorganic/organic nanocomposites." @default.
- W1507808049 created "2016-06-24" @default.
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- W1507808049 date "2004-01-01" @default.
- W1507808049 modified "2023-09-26" @default.
- W1507808049 title "Evaporation-induced self-assembly to functional nanostructures" @default.
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- W1507808049 doi "https://doi.org/10.1016/s0167-2991(04)80199-x" @default.
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