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- W1507825878 abstract "This chapter presents investigations on the synthesis, spectra, and single-crystal structure of several hydrazinium metal sulfates, oxalates, halides (chloride, bromide), and thiocyanate complexes of transition and rare earth metals. Metal oxalate complexes containing the coordinated oxalate ligand are quite well known. Hydrazinium metal halide complexes are of two types: anhydrous and hydrated. The chapter focuses on the hydrazinium chloride complexes, which are the most prevalent. Hydrazinium and thiosemicarbazide complexes of nickel can be distinguished very easily by their color, solubility, and stability. The thiosemicarbazide complex is a dark blue crystalline compound, which is not readily soluble in water and is stable indefinitely even when exposed to air. The hydrazinium complex, on the other hand, is a light blue compound, which is readily soluble in water, is hygroscopic, and decomposes when exposed to air. Finally, the chapter briefly reviews some new hydrazinium metal complexes." @default.
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- W1507825878 date "2014-01-24" @default.
- W1507825878 modified "2023-09-23" @default.
- W1507825878 title "Hydrazinium Metal Complexes" @default.
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- W1507825878 doi "https://doi.org/10.1002/9781118693599.ch05" @default.
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