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- W1508049312 abstract "The biological functioning of the nucleic acids is supposed to involve the participation of metal ions. Certain metal ions stabilize the DNA double helix while others have a strong destabilizing effect. When DNA is denatured by heating in the presence of e.g. Cu2+ ions, the double helix is reversibly renatured by cooling and subsequent addition of electrolyte (Eichhorn and Shin, 1968). In the absence of metal ions the cooling process does not produce a reversible rewinding of the two strands. This phenomena is explained by copper ions forming crosslinks between the two strands in the unwound form so as to keep them in register, making a reversible rewinding possible (Geiduschek, 1962). Many metal ions are able to bind both phosphate and base sites, and their effect on DNA depends on their relative affinity for the two types of binding sites." @default.
- W1508049312 created "2016-06-24" @default.
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- W1508049312 date "1977-01-01" @default.
- W1508049312 modified "2023-09-27" @default.
- W1508049312 title "Crystallographic Studies on Copper Complexes of Nucleic Acid Components" @default.
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- W1508049312 doi "https://doi.org/10.1007/978-94-017-6392-9_4" @default.
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