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• W1508410462 abstract "The analytical solutions for normal pulse polarography (NPP), reverse pulse polarography (RPP), and double potential step chronoamperometry for a reversible charge transfer reaction when reactant and product are adsorbed on a plane electrode following a linear isotherm have been derived. The current-potential curves in NPP and in RPP obtained from this solution are in excellent agreement with those previously reported in the literature obtained using numerical methods. Also, our solution for the limiting current becomes equivalent to that derived by Van Leeuwen et al. (J. Electroanal. Chem., 135 (1982) 13) when the condition t'/t ⪡ (' being the pulse duration) is applied. The characteristics of the double potential step chronoamperometry response, for which no solution (analytical or numerical) had been reported previously, have also been shown. A simple method to determine the adsorption coefficients of reactant and product based on the dependence of the limiting currents in NPP and in RPP on the pulse time is discussed." @default.
• W1508410462 created "2016-06-24" @default.
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• W1508410462 date "1989-05-01" @default.
• W1508410462 modified "2023-09-22" @default.
• W1508410462 title "Study of reactant and product adsorption in double potential step and related pulse techniques" @default.
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• W1508410462 doi "https://doi.org/10.1016/0022-0728(89)85099-5" @default.
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