Matches in SemOpenAlex for { <https://semopenalex.org/work/W1508484906> ?p ?o ?g. }
- W1508484906 endingPage "135" @default.
- W1508484906 startingPage "126" @default.
- W1508484906 abstract "Chemical reactions were used to synthesize 2,11,20-tris(ethanedithia)-9,18,27-trimethoxy-6,15, 24-tri-tert-butyl[3.3.3]metacyclophane 2 and 2,11-bis(ethanedithia)-9,18,27-trimethoxy-6,15,24-tri-tert-butyl[3.3.3]metacyclophane 4 from 6,15,24-tri-tert-butyl-9,18,27-trimethoxy[3.3.3]meta-cyclophane-2,11,20-trione 1 and -2,11-dione 3. The yields of 2 and 4 were 70% and 81% respectively. The conformations of the synthesized compounds 2 and 4 were studied using mainly solution Proton Nuclear Magnetic Resonance (1H NMR) spectroscopic methods. Compounds 2 and 4 were found to have a partial-cone conformation. Detailed variable temperature Proton Nuclear Magnetic Resonance studies further confirmed the partial-cone conformation for the two products, 2, 4. During the variable temperature nuclear magnetic resonance spectroscopic studies, compound 2 was found to have a coalescence temperature of about 0?C. Extraction of silver ions with compound 2 gave an extractability of 82% while the parent compound 1 showed zero (0) silver affinity. A 1:1 mol/mol mixture of compound 2 and silver ions studied by solution 1H NMR revealed a novel “Molecular Roulette” type of motion." @default.
- W1508484906 created "2016-06-24" @default.
- W1508484906 creator A5026768131 @default.
- W1508484906 creator A5030952462 @default.
- W1508484906 creator A5038301317 @default.
- W1508484906 creator A5040356329 @default.
- W1508484906 creator A5046738528 @default.
- W1508484906 creator A5048946677 @default.
- W1508484906 date "2015-01-01" @default.
- W1508484906 modified "2023-09-28" @default.
- W1508484906 title "Synthesis and Conformational Studies on [3.3.3]Metacyclophane Oligoketone Derivatives, and Their Metal Ion Recognition" @default.
- W1508484906 cites W122695614 @default.
- W1508484906 cites W1967193178 @default.
- W1508484906 cites W1991535174 @default.
- W1508484906 cites W2004404988 @default.
- W1508484906 cites W2004539885 @default.
- W1508484906 cites W2016775783 @default.
- W1508484906 cites W2021159004 @default.
- W1508484906 cites W2021432493 @default.
- W1508484906 cites W2028892325 @default.
- W1508484906 cites W2051877713 @default.
- W1508484906 cites W2053422619 @default.
- W1508484906 cites W2054898666 @default.
- W1508484906 cites W2056648038 @default.
- W1508484906 cites W2059138958 @default.
- W1508484906 cites W2059598266 @default.
- W1508484906 cites W2062305216 @default.
- W1508484906 cites W2070820029 @default.
- W1508484906 cites W2071749486 @default.
- W1508484906 cites W2083425631 @default.
- W1508484906 cites W2089101102 @default.
- W1508484906 cites W2100371338 @default.
- W1508484906 cites W2101884223 @default.
- W1508484906 cites W2106654645 @default.
- W1508484906 cites W2123801362 @default.
- W1508484906 cites W2159198776 @default.
- W1508484906 cites W2161030462 @default.
- W1508484906 cites W2185386454 @default.
- W1508484906 cites W2367562125 @default.
- W1508484906 cites W27201236 @default.
- W1508484906 cites W2950015190 @default.
- W1508484906 cites W2953161357 @default.
- W1508484906 cites W2996484261 @default.
- W1508484906 cites W421102176 @default.
- W1508484906 cites W68177526 @default.
- W1508484906 cites W973180512 @default.
- W1508484906 doi "https://doi.org/10.4236/ijoc.2015.52014" @default.
- W1508484906 hasPublicationYear "2015" @default.
- W1508484906 type Work @default.
- W1508484906 sameAs 1508484906 @default.
- W1508484906 citedByCount "3" @default.
- W1508484906 countsByYear W15084849062016 @default.
- W1508484906 countsByYear W15084849062017 @default.
- W1508484906 countsByYear W15084849062018 @default.
- W1508484906 crossrefType "journal-article" @default.
- W1508484906 hasAuthorship W1508484906A5026768131 @default.
- W1508484906 hasAuthorship W1508484906A5030952462 @default.
- W1508484906 hasAuthorship W1508484906A5038301317 @default.
- W1508484906 hasAuthorship W1508484906A5040356329 @default.
- W1508484906 hasAuthorship W1508484906A5046738528 @default.
- W1508484906 hasAuthorship W1508484906A5048946677 @default.
- W1508484906 hasBestOaLocation W15084849061 @default.
- W1508484906 hasConcept C103319777 @default.
- W1508484906 hasConcept C111429119 @default.
- W1508484906 hasConcept C115624301 @default.
- W1508484906 hasConcept C145148216 @default.
- W1508484906 hasConcept C147789679 @default.
- W1508484906 hasConcept C178790620 @default.
- W1508484906 hasConcept C185592680 @default.
- W1508484906 hasConcept C199164860 @default.
- W1508484906 hasConcept C2778624557 @default.
- W1508484906 hasConcept C71240020 @default.
- W1508484906 hasConcept C8010536 @default.
- W1508484906 hasConceptScore W1508484906C103319777 @default.
- W1508484906 hasConceptScore W1508484906C111429119 @default.
- W1508484906 hasConceptScore W1508484906C115624301 @default.
- W1508484906 hasConceptScore W1508484906C145148216 @default.
- W1508484906 hasConceptScore W1508484906C147789679 @default.
- W1508484906 hasConceptScore W1508484906C178790620 @default.
- W1508484906 hasConceptScore W1508484906C185592680 @default.
- W1508484906 hasConceptScore W1508484906C199164860 @default.
- W1508484906 hasConceptScore W1508484906C2778624557 @default.
- W1508484906 hasConceptScore W1508484906C71240020 @default.
- W1508484906 hasConceptScore W1508484906C8010536 @default.
- W1508484906 hasIssue "02" @default.
- W1508484906 hasLocation W15084849061 @default.
- W1508484906 hasOpenAccess W1508484906 @default.
- W1508484906 hasPrimaryLocation W15084849061 @default.
- W1508484906 hasRelatedWork W1526725238 @default.
- W1508484906 hasRelatedWork W1550992468 @default.
- W1508484906 hasRelatedWork W163640571 @default.
- W1508484906 hasRelatedWork W1967042914 @default.
- W1508484906 hasRelatedWork W1975858554 @default.
- W1508484906 hasRelatedWork W1983956525 @default.
- W1508484906 hasRelatedWork W1987560397 @default.
- W1508484906 hasRelatedWork W1994084766 @default.
- W1508484906 hasRelatedWork W1999415092 @default.
- W1508484906 hasRelatedWork W2005966983 @default.