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- W1508544830 abstract "The main problems are presented regarding the transfer of the active species from the solution to the support in case of metallocene /MAO polymerization catalyst. Different approaches are discussed with references to examples reported in the literature from several laboratories and authors' laboratory. In particular, evidences are reported about variation of catalytic performances induced by the fixation to the support with particular reference to conventional amorphous silica and to crystalline supports such as Y-zeolites and MCM-41 mesomorphic silica. The effect of the chemical treatment of the support surface and the role of the cocatalyst are also described. Catalyst preparation and reaction parameters are analyzed in terms of productivity and molecular features of homopolymers and copolymers obtained in the presence of supported metallocenes." @default.
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- W1508544830 date "2000-01-01" @default.
- W1508544830 modified "2023-09-25" @default.
- W1508544830 title "Supported metallocenes: monosite and multisite catalysts for olefin polymerization" @default.
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- W1508544830 doi "https://doi.org/10.1016/s0167-2991(00)80955-6" @default.
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