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• W1508942318 abstract "Abstract The use of Raman spectroscopy for the study of the molecular order in triglycerides is explored, with emphasis placed on three key spectroscopic fingerprints: (i) the CH stretching region at 3000–2700 cm −1 , (ii) the ester carbonyl (CO) stretching region at 1780–1700 cm −1 , and the CC stretching region at ∼1200–1100 cm −1 . Triglyceride polymorph and phase‐dependent changes related to the aliphatic chain and glycerol backbone conformation and packing, as well as changes in local environment, are ascertained on the basis of shifts in these bands. In particular, the ester carbonyl stretching region demonstrates clear differences between triglycerides polymorphs, as changes are seen in the number, stretching frequency, and size of the modes present. Besides, phase transition enthalpies are extracted from the Raman spectra of triglycerides studied. This chapter demonstrates that Raman spectroscopy is a viable tool for the characterization of triglycerides." @default.
• W1508942318 created "2016-06-24" @default.
• W1508942318 creator A5024025001 @default.
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• W1508942318 date "2001-12-20" @default.
• W1508942318 modified "2023-10-03" @default.
• W1508942318 title "<scp>R</scp> aman Spectroscopy for the Study of Molecular Order, Thermodynamics, and Solid–Liquid Transitions in Triacylglycerols" @default.
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• W1508942318 doi "https://doi.org/10.1002/0470027320.s8947" @default.
• W1508942318 hasPublicationYear "2001" @default.
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