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- W1508981011 abstract "Single crystals of Cs2Cd3Te4 grow as yellow plates from the reaction of Cs2Te3 with Cd and Te at 873 K; orange plates of Rb2Cd3Te4 grow from the reaction of Rb2Te3 with Cd and Te at 773 K. The structures of both compounds have been determined from single crystal X-ray diffraction data. Cs2Cd3Te4 crystallizes in the orthorhombic space group Ibam with unit cell parameters a=6.667(1) Å, b=13.010(3) Å, c=15.390(3) Å, Z=4, T=113 K. Rb2Cd3Te4 crystallizes in the monoclinic space group C2/c with unit cell parameters a=14.424(2) Å, b=15.350(2) Å, c=12.864(2) Å, β=116.249(2), Z=8, T=153 K. Both structures comprise layers of edge-shared CdTe4 tetrahedra separated by alkali metal cations; however, the connectivity of the CdTe4 tetrahedra and the stacking of the layers are different in each compound. Bandgaps of 2.48 eV for Cs2Cd3Te4 and 2.30 eV for Rb2Cd3Te4 were determined from UV/Vis diffuse reflectance measurements made at 20°C." @default.
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- W1508981011 date "2000-06-01" @default.
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- W1508981011 title "Syntheses, crystal structures, and band gaps of Cs2Cd3Te4 and Rb2Cd3Te4" @default.
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- W1508981011 doi "https://doi.org/10.1016/s0925-8388(00)00795-7" @default.
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