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• W1509002576 abstract "A new lithium-niobate (LiNbO3)-type polar compound, namely, ZnPbO3 (a = 5.41605(7) A and c = 14.33151(3) A), with closed-shell ions only was synthesized under high pressure and high temperature (8 GPa and 1273 K). A point-charge-model calculation based on atomic positions refined by Rietveld analysis of synchrotron X-ray diffraction data gave an electrical ionic polarization of 77 μC/cm2 along the hexagonal c-axis. Detailed structural analysis indicated that the contribution of Pb4+ in ZnPbO3 to the polarization was almost twice as large as that of Sn4+ in ZnSnO3. Transport measurement showed metallic behavior of ZnPbO3 from room temperature to low temperature despite the fact that both cations are closed-shell ions." @default.
• W1509002576 created "2016-06-24" @default.
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• W1509002576 date "2015-09-07" @default.
• W1509002576 modified "2023-10-03" @default.
• W1509002576 title "A new LiNbO₃-type polar oxide with closed-shell cations: ZnPbO₃" @default.
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• W1509002576 doi "https://doi.org/10.1063/1.4930034" @default.
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