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• W1510790658 abstract "A disk-shaped [Fe(III) 7 (Cl)(MeOH)6 (μ3 -O)3 (μ-OMe)6 (PhCO2 )6 ]Cl2 complex with C3 symmetry has been synthesised and characterised. The central tetrahedral Fe(III) is 0.733 Å above the almost co-planar Fe(III) 6 wheel, to which it is connected through three μ3 -oxide bridges. For this iron-oxo core, the magnetic susceptibility analysis proposed a Heisenberg-Dirac-van Vleck (HDvV) mechanism that leads to an intermediate spin ground state of S=7/2 or 9/2. Within either of these ground state manifolds it is reasonable to expect spin frustration effects. The (57) Fe Mössbauer (MS) analysis verifies that the central Fe(III) ion easily aligns its magnetic moment antiparallel to the externally applied field direction, whereas the other six peripheral Fe(III) ions keep their moments almost perpendicular to the field at stronger fields. This unusual canted spin structure reflects spin frustration. The small linewidths in the magnetic Mössbauer spectra of polycrystalline samples clearly suggest an isotropic exchange mechanism for realisation of this peculiar spin topology." @default.
• W1510790658 created "2016-06-24" @default.
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• W1510790658 date "2015-06-12" @default.
• W1510790658 modified "2023-10-10" @default.
• W1510790658 title "A Strongly Spin-Frustrated Fe^III₇Complex with a Canted Intermediate Spin Ground State of<i>S</i>=7/2 or 9/2" @default.
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• W1510790658 doi "https://doi.org/10.1002/chem.201500841" @default.
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