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- W1512442823 abstract "Abstract The reduction of tert-nitrobutane in acetonitrile has been studied by cyclic voltammetry. By the fit of data to theoretical voltammograms obtained from digital simulations, the electrochemical transfer coefficient, α , was found to be potential dependent at mercury and platinum. This result was confirmed by potential step experiments. The potential dependence of α is discussed according to Marcus theory of electron transfer and compared to the measurements of others. In addition, the electrochemical rate constant, k s , was found to depend on the size of the electrolyte cation. The rate constant decreased as the size of the tetraalkylammonium ion in the electrolyte increased. It is speculated that this effect may be partly a double layer effect resulting from differing planes of closest approach for different electrolyte cations." @default.
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- W1512442823 date "1980-01-01" @default.
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- W1512442823 title "Cyclic voltammetric study of tert-nitrobutane reduction in acetonitrile at mercury and platinum electrodes" @default.
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- W1512442823 doi "https://doi.org/10.1016/s0022-0728(80)80175-6" @default.
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