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- W151266530 abstract "Publisher Summary This chapter discusses the magnetic properties of binary rare-earth 3d-transition-metal intermetallic compounds. The basic concepts related to the intrinsic magnetic properties of the 3d-rich R n T m (R = rare earths; T = 3d heavy transition metals Mn, Fe, Co, Ni) intermetallic compounds are discussed. The study of rare-earth transition-metal intermetallic compounds has a number of interesting aspects. Owing to the wide range of intermetallics and their different stoichiometries and variable rare-earth elements, modifications of magnetic properties of 3d transition-metal and 4f rare-earth ions can be investigated systematically. These investigations illuminate the complex interactions in which the 3d and 4f electrons are involved. The rare-earth metals in their ‘normal’ state where the magnetic properties of the ion cores are well defined. The 4f electrons are positioned within the ion cores and hybridization with the conduction-band-electron states is negligible. This situation is realized for most iron- and cobalt-based compounds with 4f elements. The Ce and Yb ions, which sometimes demonstrate unusual properties connected with valence fluctuations, tend to behave quite normally in the compounds with iron or cobalt. Nevertheless, there are some anomalies in the Ce compounds that can be ascribed to a mixed-valence state of the cerium ion." @default.
- W151266530 created "2016-06-24" @default.
- W151266530 creator A5060136157 @default.
- W151266530 creator A5061399256 @default.
- W151266530 date "1993-01-01" @default.
- W151266530 modified "2023-10-17" @default.
- W151266530 title "Chapter 5 Magnetic properties of binary rare-earth 3d-transition-metal intermetallic compounds" @default.
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