Matches in SemOpenAlex for { <https://semopenalex.org/work/W1513944685> ?p ?o ?g. }
Showing items 1 to 77 of
77
with 100 items per page.
- W1513944685 endingPage "94" @default.
- W1513944685 startingPage "83" @default.
- W1513944685 abstract "The condensation reactions of tetrachloro mono (1 and 2) and bisferrocenyl spirocyclotriphosphazenes (3–5) with morpholine in tetrahydrofuran gave the partly morpholino-substituted ferrocenylphosphazenes. When the reactions were carried out with equal amounts of 1–5 and morpholine, the mono-substituted ferrocenylphosphazenes (1a, 3a–5a) formed as the major product. While the reactions were made with 1 equiv of 1–5 and 2 equiv of morpholine, the corresponding geminal–phosphazenes (1b–5b) were isolated. In addition, the condensation reactions of 1 equiv of 1–5 and 3 equiv of morpholine resulted in the formation of di-(1b–5b), tri-(2c–5c), and tetra-substituted phosphazenes. The tri-substituted compounds were isolated as major products. Some new phosphazenes have stereogenic P center(s). The stereogenic properties of 1a and 2c were investigated using 31P nuclear magnetic resonance (NMR) spectroscopy in the presence of the chiral solvating agent; (S)-(+)-2,2,2-trifluoro-1-(9′-anthryl)ethanol. The structures of all the phosphazenes were characterized by one-dimensional 1H, 13C, and 31P NMR, and two-dimensional heteronuclear single quantum coherence spectral data. The salient spectral properties of the phosphazenes were presented." @default.
- W1513944685 created "2016-06-24" @default.
- W1513944685 creator A5084655747 @default.
- W1513944685 date "2014-01-30" @default.
- W1513944685 modified "2023-09-27" @default.
- W1513944685 title "Syntheses of Chiral Phosphazenes with Stereogenic Centers: NMR Behavior in the Presence of a Chiral Solvating Agent" @default.
- W1513944685 cites W1978135921 @default.
- W1513944685 cites W1985693943 @default.
- W1513944685 cites W1997207987 @default.
- W1513944685 cites W1999473645 @default.
- W1513944685 cites W1999686760 @default.
- W1513944685 cites W2004016756 @default.
- W1513944685 cites W2004678346 @default.
- W1513944685 cites W2039588693 @default.
- W1513944685 cites W2040437539 @default.
- W1513944685 cites W2041860978 @default.
- W1513944685 cites W2059895391 @default.
- W1513944685 cites W2072359518 @default.
- W1513944685 cites W2094296539 @default.
- W1513944685 cites W2104698841 @default.
- W1513944685 cites W2158508585 @default.
- W1513944685 cites W2163746273 @default.
- W1513944685 cites W29023494 @default.
- W1513944685 doi "https://doi.org/10.1002/hc.21139" @default.
- W1513944685 hasPublicationYear "2014" @default.
- W1513944685 type Work @default.
- W1513944685 sameAs 1513944685 @default.
- W1513944685 citedByCount "20" @default.
- W1513944685 countsByYear W15139446852014 @default.
- W1513944685 countsByYear W15139446852018 @default.
- W1513944685 countsByYear W15139446852019 @default.
- W1513944685 countsByYear W15139446852021 @default.
- W1513944685 countsByYear W15139446852022 @default.
- W1513944685 countsByYear W15139446852023 @default.
- W1513944685 crossrefType "journal-article" @default.
- W1513944685 hasAuthorship W1513944685A5084655747 @default.
- W1513944685 hasConcept C134195300 @default.
- W1513944685 hasConcept C146686406 @default.
- W1513944685 hasConcept C161790260 @default.
- W1513944685 hasConcept C16838498 @default.
- W1513944685 hasConcept C178790620 @default.
- W1513944685 hasConcept C185592680 @default.
- W1513944685 hasConcept C21951064 @default.
- W1513944685 hasConcept C47849319 @default.
- W1513944685 hasConcept C486523 @default.
- W1513944685 hasConcept C71240020 @default.
- W1513944685 hasConceptScore W1513944685C134195300 @default.
- W1513944685 hasConceptScore W1513944685C146686406 @default.
- W1513944685 hasConceptScore W1513944685C161790260 @default.
- W1513944685 hasConceptScore W1513944685C16838498 @default.
- W1513944685 hasConceptScore W1513944685C178790620 @default.
- W1513944685 hasConceptScore W1513944685C185592680 @default.
- W1513944685 hasConceptScore W1513944685C21951064 @default.
- W1513944685 hasConceptScore W1513944685C47849319 @default.
- W1513944685 hasConceptScore W1513944685C486523 @default.
- W1513944685 hasConceptScore W1513944685C71240020 @default.
- W1513944685 hasIssue "2" @default.
- W1513944685 hasLocation W15139446851 @default.
- W1513944685 hasOpenAccess W1513944685 @default.
- W1513944685 hasPrimaryLocation W15139446851 @default.
- W1513944685 hasRelatedWork W2000102181 @default.
- W1513944685 hasRelatedWork W2012833358 @default.
- W1513944685 hasRelatedWork W2052856723 @default.
- W1513944685 hasRelatedWork W2168611614 @default.
- W1513944685 hasRelatedWork W2325928502 @default.
- W1513944685 hasRelatedWork W2330424792 @default.
- W1513944685 hasRelatedWork W2950264019 @default.
- W1513944685 hasRelatedWork W2981974832 @default.
- W1513944685 hasRelatedWork W3015196646 @default.
- W1513944685 hasRelatedWork W4226505362 @default.
- W1513944685 hasVolume "25" @default.
- W1513944685 isParatext "false" @default.
- W1513944685 isRetracted "false" @default.
- W1513944685 magId "1513944685" @default.
- W1513944685 workType "article" @default.