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- W1514175815 abstract "The system trans-[PtCl(CO-n-hexyl)(PPh3)2]/SnCl2 has been investigated by 31P NMR spectroscopy. In CD2Cl2 or acetone-d6 solutions two species (in equilibrium with the starting Pt complex) are observed at low temperature: one set of signals is attributed to the complex trans-[Pt(SnCl3)(CO-n-hexyl)(PPh3)2]; the other set does not show SnP coupling and it is tentatively attributed to a complex having chloride bridging the Pt and Sn metal centers. Formation of the complex trans-[Pt(SnCl3)(CO-n-hexyl)(PPh3)2] is prevented when ethanol is added to the CD3Cl2 are acetone-d6 solutions. Treatment of the CD2Cl2 or acetone-d6 solution with molecular hydrogen give n-heptanal and hydroplatinum species; this reaction does not occur in the presence of ethanol, where only a complex having chloride bridging the Pt and Sn metal centers seems to be present. The result are discussed in connection with the catalytic cycle of olefin hydroformylation promoted by the [PtCl2(PPh3)2]/SnCl2 system." @default.
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- W1514175815 date "1985-04-01" @default.
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- W1514175815 title "Metals in organic syntheses" @default.
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- W1514175815 doi "https://doi.org/10.1016/0022-328x(85)87240-5" @default.
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