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- W1514183796 abstract "The kinetics of thermal anomalies at the phase transitions in the tetraethylammonium zinc tetrachloride crystal [N(C2H5)4]2ZnCl4 has been studied by the differential scanning calorimetry method over a wide range of rate of temperature change, from 1 to 100 K min−1. The crystal is known to undergo structural phase transitions of first order at which the nucleus of the final phase characterized by a symmetry different to that of the initial phase appears and develops. The classical Johnson–Mehl–Avrami model cannot be applied to describe the two phase transitions taking place in the non-isothermal process. Making use of the isothermal process taking place below T1C, the intermediate phase has been shown to be metastable; the energy of the process is Ea = 146 ± 7 kJ mol−1, while the Avrami exponent n = 2.3 ± 0.2." @default.
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- W1514183796 date "2008-01-25" @default.
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- W1514183796 title "Kinetics of phase transitions in TEA2ZnCl4crystal" @default.
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- W1514183796 doi "https://doi.org/10.1088/0953-8984/20/7/075206" @default.
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