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- W1514503121 abstract "The location and motion of benzene molecules in NaEMT and KL zeolites have been studied by in-situ FTIR and 2H NMR techniques and correlated with zeolite structures, benzene loading and negative charge of framework oxygen atoms. The FTIR study indicates that almost all benzene molecules are facially coordinated to cations located in large cages of NaEMT and KL zeolites at any benzene loading at room temperature. 2H NMR study reveals that below 183 K for KL and 263 K for NaEMT, only a rapid spinning of benzene molecules facially adsorbed on cations around its 6-fold axis is observed. Above these temperatures, a pseudo-isotropical motion of benzene molecules, indicating the jump of benzene molecules from one adsorption site to another, occurs." @default.
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- W1514503121 date "1999-01-01" @default.
- W1514503121 modified "2023-09-25" @default.
- W1514503121 title "Behavior of benzene molecules in large pore zeolite structures as studied by FTIR and 2H NMR techniques" @default.
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- W1514503121 doi "https://doi.org/10.1016/s0167-2991(99)80221-3" @default.
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