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- W1514792233 abstract "Abstract The gas phase pyrolysis (625°C, 10−2 mbar) of cyclopentadiene, dicyclopentadiene and trimethylsilylcyclopentadiene as well as of the monosilacyclobutanes Cp data (Cp=C5H5;R=Me, t-Bu, Cl) is described. In order to investigate the reaction pathways the copyrolysis of Me2SiCH2CH2CH2 and disilanes [Me3SiSiMe3, Me2ClSiSiClMe2, Me(Vi)SiSi(Vi)Me], respectively, with cyclopentadiene has been studied under the same conditions. The surprising formation of the aromatic systems benzene (main product) and toluene is interpreted on the basis of the sequence of intramolecular reactions of the silaethene intermediate Cp(R)SiCH2 (valence isomerisation, elimination)." @default.
- W1514792233 created "2016-06-24" @default.
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- W1514792233 date "1980-05-01" @default.
- W1514792233 modified "2023-10-12" @default.
- W1514792233 title "Silaethene" @default.
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- W1514792233 doi "https://doi.org/10.1016/s0022-328x(00)85911-2" @default.
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