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- W1515080621 abstract "Cationic metal carbonyls [M(CO)m]n+, which have a positive metal charge, were prepared from Cu, Ag, Au, Pd, Pt, Rh and Ir. The M-C bonds of these compounds were mainly formed by the σ-dative bond of CO, then the ν co values were observed at a higher wavenumber than the free CO. These unstable cationic metal carbonyls were used as catalysts for the carbonylation of olefins, alcohols, dienes, aldehydes and saturated hydrocarbons to give tert-carboxylic acids in high yields at room temperature and atmospheric CO pressure." @default.
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- W1515080621 date "2003-01-01" @default.
- W1515080621 modified "2023-10-05" @default.
- W1515080621 title "41 Preparation and catalytic application of cationic metal carbonyls" @default.
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- W1515080621 doi "https://doi.org/10.1016/s0167-2991(03)80198-2" @default.
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