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- W151529992 abstract "Electrochemical reduction of phenylperfluoroalkyliodonium salts has been studied. It is shown that electrochemical reduction potential and current depend on the nature of the anion. In the case of phenylperfluoroalkyliodonium chloride, its electrocatalytic decomposition in the polar solvent has been found. Preparative electrochemical reduction of phenylheptafluoropropiliodonium tetrafluoroborate in the presence of sodium sulfinates results in the formation of corresponding sulfones and perfluoropropionic acid. The reaction proceeds by the chain radical-ion mechanism which is proved by the high current yield (0.2 F/mol)." @default.
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- W151529992 date "1991-09-01" @default.
- W151529992 modified "2023-10-04" @default.
- W151529992 title "Electrochemical synthesis of sulfones based on arylperfluoroalkyliodonium salts" @default.
- W151529992 doi "https://doi.org/10.1016/s0022-1139(00)83910-x" @default.
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