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- W1515705769 abstract "Various theoretical studies of σ-bond activation of organic molecules by transition metal complexes arereviewed. In the homolytic σ-bond activation, the d orbital energy level of the central metal is an importantfactor, as well known. At the same time, the electron-withdrawing substituent which stabilizes the sp3 orbitalaccelerates the homolytic σ-bond activation. In the heterolytic C-H σ-bond activation of RH by <TEX>$MXL_n$</TEX>, the XHbond formation is an important driving force, where <TEX>$MRL_n$</TEX> and HX are formed as products. The heterolytic σ-bond activation is also understood in terms of the electrophilic attack of the metal center to the substrate." @default.
- W1515705769 created "2016-06-24" @default.
- W1515705769 date "2003-06-20" @default.
- W1515705769 modified "2023-10-17" @default.
- W1515705769 title "Theoretical Study of C-H σ-Bond Activation and Related Reactions" @default.
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- W1515705769 doi "https://doi.org/10.5012/bkcs.2003.24.6.829" @default.
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