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- W1516392015 abstract "The synthesis of a series of cyclometallated hydrigo-iridium(III) compounds fac-IrH[C(O)ArCH2-2](PhPRR′) (Ar C6H4: R R′ OMe. Ar C6H2Me2-4,6: R Me, OEt, Ph; R′ OMe, OEt) from iridium(I) aryls Ir[ArCH3-2](CO)(PPh3)2 and phosphonites or phosphinites is reported. As a result of a reversible methyl-to-metal hydrogen transfer the tris(phosphinite) complex IrH[C(O)C6H2Me2-4,6-CH2-2](Ph2POMe)3 exists in solution in an equilibrium with Ir[C6H2Me3-2,4,6](CO)-(Ph2POMe)2 and Ph2POMe. The demetallated iridium(I) compound predominates in this equilibrium which may be shifted in favour of the metallacyclic component by addition of excess phosphinite." @default.
- W1516392015 created "2016-06-24" @default.
- W1516392015 creator A5046016273 @default.
- W1516392015 date "1983-07-01" @default.
- W1516392015 modified "2023-09-27" @default.
- W1516392015 title "Alkyl- und arylkomplexe des iridiums und rhodiums" @default.
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- W1516392015 doi "https://doi.org/10.1016/s0022-328x(00)99504-4" @default.
- W1516392015 hasPublicationYear "1983" @default.
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