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- W1516645327 abstract "The vibrationally excited oxygen in O<sub>2</sub>(<i>a</i><sup>1</sup>Δ<sub>g</sub>)-I mixture was detected by emission spectroscopy. The analysis of a luminescence spectra of oxygen molecules on O<sub>2</sub>(<i>b</i><sup>1</sup>Σ<sub>g</sub><sup>+</sup>,υ') → O<sub>2</sub>(X<sup>3</sup>Σ<sub>g</sub><sup>-</sup>,υ) transitions has shown, that vibrationally excited O<sub>2</sub>(<i>b</i><sup>1</sup>Σ<sub>g</sub><sup>+</sup>) molecules up to υ=5 are generated in the active medium of chemical oxygen-iodine laser (COIL). The highest values of relative O<sub>2</sub>(<i>b</i><sup>1</sup>Σ<sub>g</sub><sup>+</sup>,υ=1) population of 22% and O<sub>2</sub>(<i>b</i><sup>1</sup>Σ<sub>g</sub><sup>+</sup>,υ=2) of 10% are reached for I<sub>2</sub> content in an oxygen flow ≈1%. It is shown theoretically, that the relative populations of O<sub>2</sub>(X<sup>3</sup>Σ<sub>g</sub><sup>-</sup>), O<sub>2</sub>(<i>a</i><sup>1</sup>Δ<sub>g</sub>) and O<sub>2</sub>(<i>b</i><sup>1</sup>Σ<sub>g</sub><sup>+</sup>) molecules at the first and the second vibrational levels are approximately equal because of fast EE energy exchange between oxygen molecules. Up to 20% of oxygen molecules in COIL active medium are vibrationally excited." @default.
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- W1516645327 date "2004-06-16" @default.
- W1516645327 modified "2023-10-16" @default.
- W1516645327 title "<title>Detection of vibrationally-excited O<formula><inf><roman>2</roman></inf></formula> in COIL active medium</title>" @default.
- W1516645327 doi "https://doi.org/10.1117/12.558196" @default.
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