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- W1516816749 abstract "Mayvat brilliant red AF has been identified as a halogenated derivative of 3:4:9:10-dibenzopyrene-5:8-quinone (II), the latter being obtained by dehalogenation of Mayvat brilliant red AF or Indanthrene scarlet 4G with Raney nickel, aqueous sodium hydroxide and hydrogen. Reduction of (II) with aluminium tricyclohexoxide gave 3:4:9:10-dibenzopyrene (I), a potent carcinogen, which was isolated by Bonnet and Neukomm from tobacco smoke. Oxidation of 3:4:9:10-dibenzopyrene-5:8-quinone with chromic acid in glacial acetic acid gave pentaphene-5:14:8:13-diquinone (V). Reduction of (V) with aluminium tricyclohexoxide yielded pentaphene (VI). Condensation of (V) with hydrazine gave 1:2-diaza-3:4:9:10-dibenzopyrene-5:8-quinone (VII), reduction of which with aluminium tricyclohexoxide gave 1:2-diaza-3:4:9:10-dibenzopyrene (VIII)." @default.
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- W1516816749 date "1958-01-01" @default.
- W1516816749 modified "2023-10-17" @default.
- W1516816749 title "Anthraquinone and anthrone series—XXII" @default.
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- W1516816749 doi "https://doi.org/10.1016/s0040-4020(01)82611-9" @default.
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