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- W1517082247 abstract "Reversible addition fragmentation chain transfer (RAFT) ab initio emulsion polymerization of styrene using poly(acrylic acid)-b-polystyrene trithiocarbonate (AAx-b-Sty macroRAFT) as both mediator and surfactant was investigated with systematically changed y from 0 to 7 and x from 15 to 30. A well-controlled polymerization in terms of little coagulum, well predicted molecular weight and low polydispersity (PDI) (≈1.2) could only be achieved by using the macroRAFTs of hydrophile-lipophile balance (HLB) values between 13 and 20. The final latex particle size could be tuned from 80 to 172 nm in diameter simply by changing x and y values while the molecular weight was targeted the same (30 K)." @default.
- W1517082247 created "2016-06-24" @default.
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- W1517082247 date "2014-06-01" @default.
- W1517082247 modified "2023-10-11" @default.
- W1517082247 title "RAFT Ab Initio Emulsion Polymerization of Styrene Using Poly(acrylic acid)-b-polystyrene Trithiocarbonate of Various Structures as Mediator and Surfactant" @default.
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- W1517082247 doi "https://doi.org/10.1002/mren.201400010" @default.
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