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- W1517598082 abstract "Abstract The pathways of conversion were studied and the rate constants of thermolysis for meta - and para -substituted benzyl aryl ethers were measured under conditions close to the initial stages of coal liquefaction (hydrogen pressure, 8.5 MPa, 275–350 °C; solvent: tetralin). The destruction of ethers is accompanied by rearrangement into the corresponding derivatives of benzylphenol that amount to 20–25 % of the reaction products. The electron-donating substituents increase the thermolysis rate whereas the electron-accepting substituents decrease it. The effect of substituents on thermolysis rate is described by the Hammet equation with ϱ constant at 325 °C equal to −2.75." @default.
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- W1517598082 date "1988-05-01" @default.
- W1517598082 modified "2023-09-26" @default.
- W1517598082 title "Effect of the structure of coal-related model ethers on the rate and mechanism of their thermolysis" @default.
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- W1517598082 doi "https://doi.org/10.1016/0016-2361(88)90295-5" @default.
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