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• W1517919706 abstract "In fullerene anions C60n−, the n electrons outside closed shells occupy t1u triplet electronic states. Jahn–Teller (JT) coupling between these states and 5-fold h-type vibrations has important consequences for many properties of the fullerene anions. It is therefore important to understand the JT effect experienced by these ions from a theoretical point of view. We will study the cases of n=2 and 4, where the lowest adiabatic potential energy surface is found to consist of a two-dimensional trough in linear coupling. The motion of the system therefore consists of vibrations in three directions ‘across’ the trough and pseudo-rotations in two directions around the trough. Analytical expressions for states of the system that reflect this motion are obtained and the resultant energies determined." @default.
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• W1517919706 date "2003-01-01" @default.
• W1517919706 modified "2023-09-26" @default.
• W1517919706 title "Multiple Occupancy of Triply Degenerate States in Icosahedral Symmetry" @default.
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• W1517919706 doi "https://doi.org/10.1016/s0065-3276(03)44021-5" @default.
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