Matches in SemOpenAlex for { <https://semopenalex.org/work/W1518112751> ?p ?o ?g. }
- W1518112751 endingPage "318" @default.
- W1518112751 startingPage "279" @default.
- W1518112751 abstract "This chapter discusses the role of sulfur in catalytic hydrogenation reactions. One of the most severe causes of metallic catalyst poisoning is the adsorption of species containing sulfur. Sulfur-containing compounds are present in natural sources of hydrocarbons, and are found in industrial feedstocks. The poisoning of metallic catalysts by sulfur has been extensively studied, essentially on nickel, palladium, and platinum, for numerous reactions and consequently under very different experimental conditions, particularly for temperatures ranging from 300 to 1300 K. Such desorptions, depending on the metal-sulfur binding energy and the thermodynamic properties of the surface-adlayer interface, play an important role in controlling the sulfur coverage. The distribution of adsorbed sulfur on the metallic surface and the resulting effect on activity and selectivity of the metal depends on this coverage. At low coverage, for which interactions between adjacent adatoms are negligible, sulfur atoms adsorbed on a heterogeneous surface are located on sites that have the highest binding energies. At higher coverages, sulfur atoms could be gathered into islands. Catalytic reactions performed at low temperatures (below 400 K) show that adsorption of sulfur-containing compounds is then irreversible, the equilibrium being wholly displaced toward the left." @default.
- W1518112751 created "2016-06-24" @default.
- W1518112751 creator A5001585774 @default.
- W1518112751 creator A5001751235 @default.
- W1518112751 creator A5022202816 @default.
- W1518112751 creator A5024113339 @default.
- W1518112751 creator A5046088930 @default.
- W1518112751 creator A5057409505 @default.
- W1518112751 date "1990-01-01" @default.
- W1518112751 modified "2023-10-11" @default.
- W1518112751 title "Role of Sulfur in Catalytic Hydrogenation Reactions" @default.
- W1518112751 cites W1039353764 @default.
- W1518112751 cites W1161827001 @default.
- W1518112751 cites W1525536688 @default.
- W1518112751 cites W1532184096 @default.
- W1518112751 cites W1963506222 @default.
- W1518112751 cites W1963861988 @default.
- W1518112751 cites W1968666632 @default.
- W1518112751 cites W1974569571 @default.
- W1518112751 cites W1976100626 @default.
- W1518112751 cites W1978293804 @default.
- W1518112751 cites W1978393841 @default.
- W1518112751 cites W1981718898 @default.
- W1518112751 cites W1984017490 @default.
- W1518112751 cites W1988528817 @default.
- W1518112751 cites W1989960384 @default.
- W1518112751 cites W1992957983 @default.
- W1518112751 cites W1996827346 @default.
- W1518112751 cites W1999626289 @default.
- W1518112751 cites W1999696212 @default.
- W1518112751 cites W2007055176 @default.
- W1518112751 cites W2007550428 @default.
- W1518112751 cites W2008919503 @default.
- W1518112751 cites W2009396681 @default.
- W1518112751 cites W2011747554 @default.
- W1518112751 cites W2014410100 @default.
- W1518112751 cites W2015116403 @default.
- W1518112751 cites W2015137564 @default.
- W1518112751 cites W2015295556 @default.
- W1518112751 cites W2021542841 @default.
- W1518112751 cites W2022963625 @default.
- W1518112751 cites W2027214096 @default.
- W1518112751 cites W2027588209 @default.
- W1518112751 cites W2029799261 @default.
- W1518112751 cites W2032259951 @default.
- W1518112751 cites W2033405407 @default.
- W1518112751 cites W2034279857 @default.
- W1518112751 cites W2039596969 @default.
- W1518112751 cites W2040602434 @default.
- W1518112751 cites W2043423946 @default.
- W1518112751 cites W2044595192 @default.
- W1518112751 cites W2045648544 @default.
- W1518112751 cites W2047120554 @default.
- W1518112751 cites W2054526311 @default.
- W1518112751 cites W2055668512 @default.
- W1518112751 cites W2059084127 @default.
- W1518112751 cites W2063051042 @default.
- W1518112751 cites W2067155963 @default.
- W1518112751 cites W2068356566 @default.
- W1518112751 cites W2077387864 @default.
- W1518112751 cites W2080440355 @default.
- W1518112751 cites W2088288139 @default.
- W1518112751 cites W2323366602 @default.
- W1518112751 cites W2467275102 @default.
- W1518112751 cites W2489486953 @default.
- W1518112751 cites W2516836939 @default.
- W1518112751 cites W2621791951 @default.
- W1518112751 cites W2622865232 @default.
- W1518112751 cites W2622942753 @default.
- W1518112751 cites W2942428273 @default.
- W1518112751 cites W2950510457 @default.
- W1518112751 cites W2951911311 @default.
- W1518112751 cites W310491095 @default.
- W1518112751 cites W4211040474 @default.
- W1518112751 cites W4248464768 @default.
- W1518112751 cites W4246369462 @default.
- W1518112751 doi "https://doi.org/10.1016/s0360-0564(08)60367-3" @default.
- W1518112751 hasPublicationYear "1990" @default.
- W1518112751 type Work @default.
- W1518112751 sameAs 1518112751 @default.
- W1518112751 citedByCount "84" @default.
- W1518112751 countsByYear W15181127512012 @default.
- W1518112751 countsByYear W15181127512013 @default.
- W1518112751 countsByYear W15181127512014 @default.
- W1518112751 countsByYear W15181127512017 @default.
- W1518112751 countsByYear W15181127512018 @default.
- W1518112751 countsByYear W15181127512021 @default.
- W1518112751 crossrefType "book-chapter" @default.
- W1518112751 hasAuthorship W1518112751A5001585774 @default.
- W1518112751 hasAuthorship W1518112751A5001751235 @default.
- W1518112751 hasAuthorship W1518112751A5022202816 @default.
- W1518112751 hasAuthorship W1518112751A5024113339 @default.
- W1518112751 hasAuthorship W1518112751A5046088930 @default.
- W1518112751 hasAuthorship W1518112751A5057409505 @default.
- W1518112751 hasConcept C150394285 @default.
- W1518112751 hasConcept C161790260 @default.
- W1518112751 hasConcept C178790620 @default.
- W1518112751 hasConcept C179104552 @default.