Matches in SemOpenAlex for { <https://semopenalex.org/work/W1519817812> ?p ?o ?g. }
Showing items 1 to 64 of
64
with 100 items per page.
- W1519817812 endingPage "152" @default.
- W1519817812 startingPage "143" @default.
- W1519817812 abstract "The effect of hydrogen chloride on the decomposition of poly(vinyl chloride) (PVC) has been studied and a mechanism for the autocatalysis is given. The chloride ion formed upon dissociation of the hydrogen chloride is a strong base in the medium of the reaction, and hence constitutes the active species. Therefore, the acceleration of the decomposition of PVC can be prevented by either removing the free acid from the system with the aid of an acid acceptor or adding a complexing agent such as ferric chloride. Der Einfluß von Chlorwasserstoff auf die Zersetzung von Polyvinylchlorid (PVC) wurde untersucht. Aufgrund der Ergebnisse wurde eine Hypothese über den Mechanismus der Autokatalyse entwickelt. Das bei Dissoziation des Chlorwasserstoffs entstehende Chlorid-Ion wirkt im betreffenden Reaktionsmedium wie eine starke Base und bildet somit das aktive Element. Die Beschleunigung der Zersetzung des PVC läßt sich daher vermeiden, wenn man entweder die freie Säure mit Hilfe eines Säure-Acceptors aus dem System entfernt oder einen Komplexbildner zusetzt, wie z. B. Ferrichlorid." @default.
- W1519817812 created "2016-06-24" @default.
- W1519817812 creator A5006050136 @default.
- W1519817812 creator A5023718150 @default.
- W1519817812 date "1969-09-10" @default.
- W1519817812 modified "2023-10-16" @default.
- W1519817812 doi "https://doi.org/10.1002/apmc.1969.050080110" @default.
- W1519817812 hasPublicationYear "1969" @default.
- W1519817812 type Work @default.
- W1519817812 sameAs 1519817812 @default.
- W1519817812 citedByCount "40" @default.
- W1519817812 countsByYear W15198178122012 @default.
- W1519817812 countsByYear W15198178122015 @default.
- W1519817812 countsByYear W15198178122018 @default.
- W1519817812 countsByYear W15198178122019 @default.
- W1519817812 countsByYear W15198178122020 @default.
- W1519817812 crossrefType "journal-article" @default.
- W1519817812 hasAuthorship W1519817812A5006050136 @default.
- W1519817812 hasAuthorship W1519817812A5023718150 @default.
- W1519817812 hasConcept C155647269 @default.
- W1519817812 hasConcept C15920480 @default.
- W1519817812 hasConcept C161790260 @default.
- W1519817812 hasConcept C178790620 @default.
- W1519817812 hasConcept C185592680 @default.
- W1519817812 hasConcept C188027245 @default.
- W1519817812 hasConcept C2778695967 @default.
- W1519817812 hasConcept C2780534640 @default.
- W1519817812 hasConcept C2781087020 @default.
- W1519817812 hasConcept C2781460079 @default.
- W1519817812 hasConcept C37263863 @default.
- W1519817812 hasConcept C521977710 @default.
- W1519817812 hasConceptScore W1519817812C155647269 @default.
- W1519817812 hasConceptScore W1519817812C15920480 @default.
- W1519817812 hasConceptScore W1519817812C161790260 @default.
- W1519817812 hasConceptScore W1519817812C178790620 @default.
- W1519817812 hasConceptScore W1519817812C185592680 @default.
- W1519817812 hasConceptScore W1519817812C188027245 @default.
- W1519817812 hasConceptScore W1519817812C2778695967 @default.
- W1519817812 hasConceptScore W1519817812C2780534640 @default.
- W1519817812 hasConceptScore W1519817812C2781087020 @default.
- W1519817812 hasConceptScore W1519817812C2781460079 @default.
- W1519817812 hasConceptScore W1519817812C37263863 @default.
- W1519817812 hasConceptScore W1519817812C521977710 @default.
- W1519817812 hasIssue "1" @default.
- W1519817812 hasLocation W15198178121 @default.
- W1519817812 hasOpenAccess W1519817812 @default.
- W1519817812 hasPrimaryLocation W15198178121 @default.
- W1519817812 hasRelatedWork W2003395557 @default.
- W1519817812 hasRelatedWork W2012236259 @default.
- W1519817812 hasRelatedWork W2075936063 @default.
- W1519817812 hasRelatedWork W2094092654 @default.
- W1519817812 hasRelatedWork W2316560477 @default.
- W1519817812 hasRelatedWork W2354440324 @default.
- W1519817812 hasRelatedWork W2606130786 @default.
- W1519817812 hasRelatedWork W2911842645 @default.
- W1519817812 hasRelatedWork W2948395022 @default.
- W1519817812 hasRelatedWork W2951953005 @default.
- W1519817812 hasVolume "8" @default.
- W1519817812 isParatext "false" @default.
- W1519817812 isRetracted "false" @default.
- W1519817812 magId "1519817812" @default.
- W1519817812 workType "article" @default.