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- W1520003102 abstract "Four chiral stationary phases (CSPs) derived from N-(3.5-dinitrobenzoyl)tyrosine were synthesized. They only differ in one potential site of interaction, viz., the functional group directly bound to the asymmetric centre. This was evaluated in terms of its dominant character according to the selectivity parameters χe, χd and χn of an equivalent solvent. For this purpose, the enantiomeric separation of nine racemates using liquid and subcritical fluid chromatographic modes was performed on the four CSPs. The chromatographic data allowed the determination of the nature of the interaction occurring at the modular site of interaction depending on the solute structure. The influence of the nature of the polar modifier on this interaction was also investigated." @default.
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- W1520003102 date "1991-01-01" @default.
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- W1520003102 title "Chiral recognition mechanisms on chiral stationary phases derived from tyrosine" @default.
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- W1520003102 doi "https://doi.org/10.1016/s0021-9673(01)88803-8" @default.
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