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• W1520161246 abstract "Three ionic complexes, [Ag(Hmimt)](NO3), [Ag(Hmimt)2](NO3) and [Ag(Hmimt)3(NO3) (Hmimt = 1-methyl-2(3H)-imidazolinethione), were synthesized by reacting AgNO3 with Hmimt and characterized spectroscopically (mass, IR and 1H, 13C, 15N and 109Ag NMR). The structure of [Ag(Hmimt)3](NO3) was determined by X-ray crystallography. In this compound, which crystallizes in the monoclinic system (space group P21/n; a = 7.621(2), b = 27.281(5), c = 10.256(4) Å, β = 107.89(1)°, Z = 4) the Ag+ ion is trigonally coordinated in the [Ag(Hmimt)3]+ cation, with a mean Ag⋯S distance of 2.489 Å. The shortest Ag3.O distance is 2.929 Å, and the crystal lattice features an extensive network of hydrogen bonds." @default.
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• W1520161246 date "1996-01-01" @default.
• W1520161246 modified "2023-09-25" @default.
• W1520161246 title "Complexes of Ag(I) with 1-methyl-2(3H)-imidazolinethione. The crystal structure of tris[1-methyl-2(3H)-imidazolinethione]-silver(I) nitrate" @default.
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• W1520161246 doi "https://doi.org/10.1016/0020-1693(95)04729-8" @default.
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