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• W1520263577 abstract "The effect of sulfur and copper contents on the activity of Cu/sulfated-zirconia (SZ) catalysts, in the selective reduction of NO byn-decane, were investigated in the 298–723 K temperature range. ZrO2and SZ solids exhibited no activity below 773 K. Cu/ZrO2is active and selective at low temperature (<600 K) but oxidises selectively NO to NO2at higher temperatures. By contrast, whatever the temperature, a 100% selectivity to N2is obtained with Cu/SZ catalysts. The highest activity is reached with the catalyst containing the highest number of acid sites which corresponds to a sulfur content close to the amount required to form a sulfate monolayer. Acidity plays a significant role only at temperatures above 600 K, where it is concluded that a bifunctional mechanism governs the reduction of NO to N2." @default.
• W1520263577 created "2016-06-24" @default.
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• W1520263577 date "1998-04-01" @default.
• W1520263577 modified "2023-09-24" @default.
• W1520263577 title "Selective Catalytic Reduction of Nitric Oxide byn-Decane on Cu/Sulfated-Zirconia Catalysts in Oxygen Rich Atmosphere" @default.
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• W1520263577 doi "https://doi.org/10.1006/jcat.1998.1972" @default.
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