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- W1520316188 abstract "When 2-sodionorbornene, prepared by the metalation of norbornene with amylsodium, reacts with benzaldehyde, the products formed are benzyl alcohol, benzoic acid, benzyl benzoate, and endo-2-norbornyl phenyl ketone. None of the anticipated 2-norbornenyl phenyl carbinol was found in the product mixture. Benzophenone reacts with 2-sodionorbornene to produce a mixture of endo- and exo-2-hydroxy-3-benzhydrylidenenorbornane in which the exo isomer is believed to predominate. Accompanying this mixture of carbinols is a trace of the corresponding ketone, 3-benzhydrylidenenorcamphor, as well as benzhydrol and benzopinacol. The exo carbinol is produced when the norcamphor derivative is reduced with sodium borohydride and a conformational argument is advanced to account for this result." @default.
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- W1520316188 date "1965-10-01" @default.
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- W1520316188 title "Organometallic chemistry" @default.
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- W1520316188 doi "https://doi.org/10.1016/s0022-328x(00)88831-2" @default.
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