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- W1520365005 abstract "A rapid and reliable determination of chromium was developed based on bromate oxidation of chromium(III) to chromium(VI). The reaction is complete under weakly acidic conditions and with cobalt(II) present as a catalyst. Unreacted bromate and chromium(VI) are then reduced with sulfite to bromide and chromium(III). The bromide is titrated potentiometrically with mercury(I) using a silver amalgam indicator electrode. Iron(III) if present is reduced by sulfite to iron(II) and does not interfere. Some binary and ternary metal mixtures containing chromium can be resolved by the determination of chromium, alone or with another metal, by the above procedure coupled with procedures for further sample portions involving the potentiometric titration of unreacted CyDTA or iodide, or both, with mercury(II)." @default.
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- W1520365005 date "1981-12-01" @default.
- W1520365005 modified "2023-09-26" @default.
- W1520365005 title "Applications involving oxidation with potassium bromate" @default.
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- W1520365005 doi "https://doi.org/10.1016/0026-265x(81)90136-3" @default.
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