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• W1520403645 abstract "Absorption spectroscopy in the vacuum ultraviolet (VUV) domain was performed on the hydrogen-deuteride molecule with a novel Fourier-transform spectrometer based upon wavefront division interferometry. This unique instrument, which is a permanent endstation of the undulator-based beamline DESIRS on the synchrotron SOLEIL facility, opens the way to Fourier-transform spectroscopy in the VUV range. The HD spectral lines in the Lyman and Werner bands were recorded in the 87–112 nm range from a quasi-static gas sample in a windowless configuration and with a Doppler-limited resolution. Line positions of some 268 transitions in the Lyman bands and 141 transitions in the Werner bands were deduced with uncertainties of 0.04 cm−1 (1σ) which correspond to Δλ/λ ∼ 4 × 10−7. This extensive laboratory database is of relevance for comparison with astronomical observations of H2 and HD spectra from highly redshifted objects, with the goal of extracting a possible variation of the proton-to-electron mass ratio (μ = m p /m e ) on a cosmological time scale. For this reason also calculations of the so-called sensitivity coefficients K i were performed in order to allow for deducing constraints on Δμ/μ. The K i coefficients, associated with the line shift that each spectral line undergoes as a result of a varying value for μ, were derived from calculations as a function of μ solving the Schrödinger equation using ab initio potentials." @default.
• W1520403645 created "2016-06-24" @default.
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• W1520403645 date "2010-03-20" @default.
• W1520403645 modified "2023-09-26" @default.
• W1520403645 title "Fourier-transform spectroscopy of HD in the vacuum ultraviolet at λ = 87–112 nm" @default.
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• W1520403645 doi "https://doi.org/10.1080/00268971003649307" @default.
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