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• W1520428077 abstract "Dimethyltin dichloride and the potentially tridentate ligand Me2NCH[OEt)2PO]2 form a 1:1 complex I which crystallizes in the space group I4−m as dimers {Me2NCH[(OEt)2PO]2 · Me2SnCl2}2 in which the oxygen atoms of one phosphoryl ligand are bridging two tin atoms each having a distorted octahedral coordination sphere, the first example of this bridging mode in the coordination chemistry of dialkyltin dihalides. Molecular parameters are: SnC 2.16(2) and 2.11(2), SnCl 2.481(5), SnO 2.48(2) Å; CSnC 156.6(8), ClSnCl 90.8(2), OSnO 98.1(4), ClSnCl 90.8(2), C(1)SnCl 99.4(6)°. The metal and ligand atoms form a twisted 12-membered ring in which the nitrogen atoms are clearly outside the coordination spheres of the metals. 119Sn Mössbauer data are correlated with the observed deviation of 153° from an ideal 180° geometry for the CSnC bond angle." @default.
• W1520428077 created "2016-06-24" @default.
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• W1520428077 date "1991-04-01" @default.
• W1520428077 modified "2023-10-12" @default.
• W1520428077 title "{Me2NCH(EtO)2PO]2 · Me2SnCl2}-dimer:" @default.
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• W1520428077 doi "https://doi.org/10.1016/0022-328x(91)86309-e" @default.
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