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- W1520651520 abstract "In search of new systems with a photoexcited redox pair which exhibits a strong and stable photoinduced absorption band to understand the photophyscial and photochemical properties of electron transfer between fullernes (C60/C70) and organic donor[N,N,N’,N’-tetra(p-methylphenyl)-4,4’-diamino-1,1’-diphenyl sulphide(TPDAS)],we studied characteristic absorption spectra in the near-IR region obtained from 532nm nanosecond laser flash photolysis of a mixture of the fullerenes (C60/C70) and TPDAS in polar solvents.When fullerenes (C60/C70)were photoexcithed,the rise of the radical anion of fullerenes (C60/C70)with the rapid decay of their excited triplet states were observed in benzonitrile.It can be deduced that the electron transfer reaction does take place from TPDAS to excithed triplet state of rullerens(C60/C70).The rate consants(ket)and quantum yiekls(φet) of this process have been also evaluated." @default.
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- W1520651520 date "2002-01-01" @default.
- W1520651520 modified "2023-09-23" @default.
- W1520651520 title "Transient Absorption Spectral characterization of Electron Transfer between Fullerenes(C60/C70)and N,N,N’,N’—Tetra(p—methylphenyl)—4,4’—diamino—1,1’—diphenyl Sulphide(TPDAS)" @default.
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